Preparation of platinum and palladium films by MOCVD and their electrochemical properties

Platinum and palladium films with various compositions and structures were prepared by metal organic chemical vapour deposition (MOCVD) by controlling the deposition conditions. The films were deposited as electrodes on zirco nia solid electrolyte and their electrochemical properties were examined by impedance spectroscopy. Cal bon containing (Pt-C and Pd-C) films consisted of agglomerated fine particles (2-5 nm in diameter) and exhibited higher e lectrode conductivities than conventional Pt paste electrodes at temperatur es below 873 K. However, sintering of the fine particles and/or oxidation o f impurity carbon or Pd spoil the electrochemical performance. On the other hand two phase Pt-ZrO2 films show promise as electrode materials for zirco nia electrolyte at low temperatures because of their higher conductivity th an Pt paste electrodes (below 973 K) and their thermal stability.