Preparation of bicyclic phosphonic and phosphinic amides via N -> C migration of phosphorus

Authors
He, ZJ Modro, TA
Citation
Zj. He et Ta. Modro, Preparation of bicyclic phosphonic and phosphinic amides via N -> C migration of phosphorus, SYNTHESIS-S, (4), 2000, pp. 565-570
Citations number
17
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
4
Year of publication
2000
Pages
565 - 570
Database
ISI
SICI code
0039-7881(200004):4<565:POBPAP>2.0.ZU;2-0
Abstract
New phosphonic diamides and phosphinic amides of the 4,7,10-triaza-1 lambda (5)-phosphabicyclo[5.3.0]decane and 4,7,10-triaza-1 lambda(5)-phosphabicycl o[5. 5.0]dodecane structures were prepared from bicyclic phosphoric triamid es via the lithiation-induced N-->C migration of phosphorus, followed by pr oton or haloalkane quenching.