A new example of dynamic kinetic resolution: aminolysis of alpha-sulfinyl gamma-unsaturated dithioesters

Authors
Alayrac, C Metzner, P
Citation
C. Alayrac et P. Metzner, A new example of dynamic kinetic resolution: aminolysis of alpha-sulfinyl gamma-unsaturated dithioesters, TETRAHEDR L, 41(15), 2000, pp. 2537-2539
Citations number
7
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
15
Year of publication
2000
Pages
2537 - 2539
Database
ISI
SICI code
0040-4039(20000408)41:15<2537:ANEODK>2.0.ZU;2-U
Abstract
The aminolysis of (2S*,SS*)-dithioesters 1a-d by dimethylamine proceeded un der dynamic kinetic control, affording (2R*,SS*)-thioamides 2a-d with rever se configuration at the asymmetric carbon centre. (C) 2000 Elsevier Science Ltd. All rights reserved.