R. Metzler et J. Klafter, Kramers' escape problem with anomalous kinetics: non-exponential decay of the survival probability, CHEM P LETT, 321(3-4), 2000, pp. 238-242
Systems where multiple trapping or other manifestations of disorder lead to
a non-local temporal evolution which results in the macroscopic observatio
n of anomalous kinetics, are shown to exhibit a non-exponential, Mittag-Lef
fler decay in Kramers-type escape problems. The detailed behaviour of the s
urvival probability is studied, and it is demonstrated that the associated
escape rate is time dependent, exhibiting a turnover from a self-similar to
a logarithmic pattern. Comparisons to experiment, and to local models are
drawn. (C) 2000 Elsevier Science B.V. All rights reserved.