Lithium-excess binary clusters LinFn - 1 (n = 2-9) were detected by photoio
nization time-of-flight mass spectrometry in a supersonic cluster beam gene
rated by a laser ablation of a solid mixture of Lithium fluoride and nitrid
e. Laser power dependence of the Li2F+ signal intensity has indicated that
the ionization energy of the hyperlithiated Li2F molecule is lower than 4.6
6 eV. The theoretical vertical ionization energy obtained by the CCSD(T)/6-
311 + G(d)//B3LYP/6-311 + G(d) calculations are 4.47 eV. No nitrogen-contai
ning clusters were detected. The absence of Li4N is ascribed to the exother
micity of the reaction, 2Li(3)N --> N-2 + Li-6. (C) 2000 Elsevier Science B
.V. All rights reserved.