The phenolic composition of red and white wines from four Spanish Appellati
ons of Origin (official classification of Spanish wines) was investigated.
Different hydroxybenzoic and hydroxycinnamic acids, catechins, procyanidins
, alcohols, stilbenes and flavonols were identified. Additionally, the keto
ne 2,3-dihydroxy-1-guaiacylpropan-1-one was identified for the first time i
n red wines aged in oak barrels. The concentration of most of the phenolic
compounds quantified was higher in red wines than in white wines, as would
be expected from the different methods of vinification and the grape variet
ies used. These differences could also contribute to differences in the ant
ioxidant ability of these wines. The multivariate analysis applied to the p
henolic compounds quantified allowed the relationships among these compound
s to be examined and the origin of the wines to be distinguished.