Monte Carlo hyperspherical description of helium cluster excited states

Citation
D. Blume et Ch. Greene, Monte Carlo hyperspherical description of helium cluster excited states, J CHEM PHYS, 112(18), 2000, pp. 8053-8067
Citations number
64
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
112
Issue
18
Year of publication
2000
Pages
8053 - 8067
Database
ISI
SICI code
0021-9606(20000508)112:18<8053:MCHDOH>2.0.ZU;2-S
Abstract
The J=0 many-body Schrodinger equation for He-4(N) clusters with N=3-10 is solved numerically by combining Monte Carlo methods with the adiabatic hype rspherical approximation. We find ground state and excited state energies f or these systems with an adiabatic separation scheme that reduces the probl em to motion in a one-dimensional effective potential curve as a function o f the hyperspherical radius R. We predict the number of J=0 bound states fo r these clusters, and also the He+HeN-1 elastic scattering lengths up to N= 10. For N=5-10, these are the first such calculations reported. (C) 2000 Am erican Institute of Physics. [S0021-9606(00)01817-1].