We study numerically and analytically the turbulent diffusion characteristi
cs in a low-Froude-number turbulent shear flow beneath a free surface. In t
he numerical study, the Navier-Stokes equations are solved directly subject
to viscous boundary conditions at the free surface. From an ensemble of su
ch simulations, we find that a boundary layer develops at the free surface
characterized by a fast reduction in the value of the eddy viscosity. As th
e free surface is approached, the magnitude of the mean shear initially inc
reases over the boundary (outer) layer, reaches a maximum and then drops to
zero inside a much thinner inner layer. To understand and model this behav
iour, we derive an analytical similarity solution for the mean flow. This s
olution predicts well the shape and the time-scaling behaviour of the mean
flow obtained in the direct simulations. The theoretical solution is then u
sed to derive scaling relations for the thickness of the inner and outer la
yers. Based on this similarity solution, we propose a free-surface function
model for large-eddy simulations of free-surface turbulence. This new mode
l correctly accounts for the variations of the Smagorinsky coefficient over
the free-surface boundary layer and is validated in both a priori and a po
steriori tests.