Effect of experimental conditions on ethylene polymerization with in-situ-supported metallocene catalyst

Authors
Chu, KJ Soares, JBP Penlidis, A
Citation
Kj. Chu et al., Effect of experimental conditions on ethylene polymerization with in-situ-supported metallocene catalyst, J POL SC PC, 38(10), 2000, pp. 1803-1810
Citations number
22
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
ISSN journal
0887624X → ACNP
Volume
38
Issue
10
Year of publication
2000
Pages
1803 - 1810
Database
ISI
SICI code
0887-624X(20000515)38:10<1803:EOECOE>2.0.ZU;2-B
Abstract
Ethylene polymerization was carried out with a novel in-situ-supported meta llocene catalyst that eliminates the need for a supporting step before poly merization. The influence of the metallocene amount, aluminum to zirconium mole ratio, temperature, pressure, and cocatalyst type on polymerization ki netics and molecular weight distribution of the produced polyethylene was s tudied. (C) 2000 John Wiley & Sons, Inc.