CO+ and N-2(+) are separated with resolution of 11,000 [full width half max
imum (FWHM)] using a conventional quadrupole mass spectrometer by applying
square wave voltages to the entrance and exit lenses to trap or reflect the
ions for multiple passes. A resolution of 22,000 (FWHM) with 63% of the to
tal signal remaining is attained using multiple passes when ions are stored
between injection pulses. Gated ion extraction also reduces the mass shift
and number and intensity of artifact peaks and permits better resolution c
ompared to the performance obtained when the ions are injected continuously
. (C) 2000 American Society for Mass Spectrometry.