Synthesis of Al8B4C7 and its oxidation properties in air

Citation
Tm. Wang et A. Yamaguchi, Synthesis of Al8B4C7 and its oxidation properties in air, J CERAM S J, 108(4), 2000, pp. 375-380
Citations number
14
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
ISSN journal
09145400 → ACNP
Volume
108
Issue
4
Year of publication
2000
Pages
375 - 380
Database
ISI
SICI code
0914-5400(200004)108:4<375:SOAAIO>2.0.ZU;2-B
Abstract
Al8B4C7 has been synthesized and its oxidation properties have been evaluat ed in both powder and sintered state. Al8B4C7 can be synthesized at above 1 250 degrees C by using Al + B4C + C as a starting material mixture. At 1800 degrees C, no other phase could be identified. The process is achieved via gas phase. In the temperature range 700-1000 degrees C, the results show t hat oxidation occurred by a parabolic kinetic process, the activation energ y of the process is 25.8 kJ/mol, indicating that Al8B4C7 powder is liable t o oxidation, A sintered pure Al8B4C7 body cannot be satisfactorily used in air at temperatures higher than 1200 degrees C because of its low oxidation resistance.