A new bifunctional coupling agent: Synthesis and model reactions

Citation
L. Jakisch et al., A new bifunctional coupling agent: Synthesis and model reactions, MACRO SYMP, 149, 2000, pp. 237-243
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR SYMPOSIA
ISSN journal
10221360 → ACNP
Volume
149
Year of publication
2000
Pages
237 - 243
Database
ISI
SICI code
1022-1360(200001)149:<237:ANBCAS>2.0.ZU;2-C
Abstract
The preparation of a new bifunctional coupling agent with one oxazoline gro up and one oxazinone group has been described. Model reactions with dodecan oic acid, benzoic acid, n-dodecyl alcohol and n-dodecylamine in melt eviden ced that both carboxylic acids react selectively with the oxazoline group w hereas the oxazinone group is exclusively attacked by the amino and the hyd roxy compound, respectively. In blends of amino group terminated polyethers with a carboxy group containing polyethylene the new coupling agent has pr oven very effective.