Based on segregation data, determined with profiling techniques, we analyze
surface phase diagram of binary liquid mixtures composed of random olefini
c copolymers. Blends with extended- and small- critical point wetting regim
es are discussed. First observation of wetting transition is presented. Sur
face enrichment-depletion duality, a phenomenon prerequisite to the 2(nd) o
rder wetting transition, is described.