The microstructure of the low-temperature plasma-nitrided layer on AISI 304
austenitic stainless steel was studied by transmission electron microscopy
(TEM). The results show that the surface of the layer consists of a supers
aturated solid solution (gamma'(N)) based on the gamma'-Fe4N phase whose el
ectron diffraction pattern (EDP) has a strong diffuse scattering effect res
ulting from supersaturating nitrogen (above 20 at, pct) and [110] streaks a
rising from matrix elastic strain due to the formation of paired or cluster
ed Cr-N. The latter is due to the N above the 20 at. pct gamma'-Fe4N-phase
value and leads to a lattice parameter that is greater than that of the gam
ma'-Fe4N phase. The subsurface of the layer is composed of a supersaturated
solid solution based on gamma-austenite, which is an expanded austenite, g
amma(N). Its morphology shows the basketweave or "tweedlike" contrast consi
sting of so-called stacking fault precipitates having twin relationships wi
th the matrix whose EDP shows diffuse scattering streaks with certain direc
tions. The epsilon martensite transformation was observed in the subsurface
of the layer. The increase in stacking faults compared with the original s
tainless steel and formation of epsilon martensite in the subsurface of the
layer indicate that nitrogen lowers the stacking fault energy of austenite
.