N. Matsushita et al., FERROMAGNETIC CHARACTERISTICS OF A PEROVSKITE-TYPE OF (LA, SR)MNO3 FILMS DEPOSITED BY KR SPUTTERING, Journal de physique. IV, 7(C1), 1997, pp. 629-630
La1-xSrxMnO3 films about 4000A thick were deposited by sputtering from
the targets with composition of La0.76Sr0.24Mn0.78O3.0-y in the gas m
ixture of Kr and O-2. Although the orientation of (110) in which metal
lic ions are most closely packed was preferential for films deposited
in the gas mixture of Ar and Oz, the orientation of (111) in which lar
ge ions such as O2-, La3+ and Sr2+ are most closely packed was also ob
served in the X-ray diffraction diagrams. The maximum saturation magne
tization of the as-deposited films in Kr and O-2 was 0.17 kG and it in
creased up to 2.4 kG for the film post-annealed at 1000 degrees C for
3 hours in oxygen atmosphere. This value was larger than that of the f
ilm deposited in Ar and O-2 and annealed under the same condition. it
seemed that the recoiled particles to the growing film surface and the
atoms incorporated into the film were decreased in sputtering process
by using Kr and therefore, larger 4 pi M-s was obtained.