The application of ceric ammonium nitrate in the synthesis of carbodiazones

Authors
Xiao, JP Wang, YL Jia, XS Wang, XY Wang, H
Citation
Jp. Xiao et al., The application of ceric ammonium nitrate in the synthesis of carbodiazones, SYN COMMUN, 30(10), 2000, pp. 1807-1812
Citations number
5
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
30
Issue
10
Year of publication
2000
Pages
1807 - 1812
Database
ISI
SICI code
0039-7911(2000)30:10<1807:TAOCAN>2.0.ZU;2-U
Abstract
The preparation of bisaryl carbodiazone compounds from the aryl substituted carbazides with Ceric Ammonium Nitrate (CAN) has been reported for the fir st time in excellent yields (80-91%). This method only needs simple instrum ents and short reaction time. A possible mechanism has been suggested.