Rearrangement of the trans-tricyclo[4.2.0.0(1,3)]oct-4-enyl Skeleton

Authors
Koltun, ES Kass, SR
Citation
Es. Koltun et Sr. Kass, Rearrangement of the trans-tricyclo[4.2.0.0(1,3)]oct-4-enyl Skeleton, TETRAHEDRON, 56(17), 2000, pp. 2591-2594
Citations number
10
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
17
Year of publication
2000
Pages
2591 - 2594
Database
ISI
SICI code
0040-4020(20000421)56:17<2591:ROTTS>2.0.ZU;2-V
Abstract
The acetolysis of a tosylate with a novel tricyclic skeleton was examined. Two major products (a tosylate and an acetate) are formed and both are the result of a skeletal rearrangement. A mechanism to account for the observed products is proposed and preliminary kinetic data are reported. (C) 2000 E lsevier Science Ltd. All rights reserved.