Palladium-catalyzed acetoxylation of cyclic allyl phosphonates in the presence of isopentyl nitrite and using molecular oxygen as final oxidant

Authors
Attolini, M Peiffer, G Maffei, M
Citation
M. Attolini et al., Palladium-catalyzed acetoxylation of cyclic allyl phosphonates in the presence of isopentyl nitrite and using molecular oxygen as final oxidant, TETRAHEDRON, 56(17), 2000, pp. 2693-2697
Citations number
31
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
17
Year of publication
2000
Pages
2693 - 2697
Database
ISI
SICI code
0040-4020(20000421)56:17<2693:PAOCAP>2.0.ZU;2-X
Abstract
The palladium-catalyzed acetoxylation of cyclic dialkyl allyl phosphonates is effected using palladium chloride as catalyst, in the presence of isopen tyl nitrite in acetic acid under an oxygen atmosphere. The proposed mechani sm for the reaction involves a palladium nitro-nitroso redox couple. (C) 20 00 Elsevier Science Ltd. All rights reserved.