Convenient synthesis of thiols and disulfides in the polyfluorinated series incorporating a butylic spacer

Citation
N. Mureau et al., Convenient synthesis of thiols and disulfides in the polyfluorinated series incorporating a butylic spacer, TETRAHEDR L, 41(16), 2000, pp. 2885-2889
Citations number
35
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
16
Year of publication
2000
Pages
2885 - 2889
Database
ISI
SICI code
0040-4039(20000415)41:16<2885:CSOTAD>2.0.ZU;2-1
Abstract
New fluorinated thiols R-F(CH2)(p)SH and disulfides [R-F(CH2)(p)S](2) conta ining a butylic spacer (p=4) between the perfluorinated part and the thiol (or disulfide) function were easily obtained in good yields with a purity h igher than 98%. This allows us to obtain homologues (p>4) for their use as synthetic intermediates or as constituents for molecular organized systems. (C) 2000 Elsevier Science Ltd. All rights reserved.