Synthesis of a novel azobenzene-based trihydroxamate siderophore and photoregulation of its ferric complex structure

Authors
Masuda, T Asari, S Tamagaki, S Nagasaki, T
Citation
T. Masuda et al., Synthesis of a novel azobenzene-based trihydroxamate siderophore and photoregulation of its ferric complex structure, TETRAHEDR L, 41(14), 2000, pp. 2411-2414
Citations number
19
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
14
Year of publication
2000
Pages
2411 - 2414
Database
ISI
SICI code
0040-4039(20000401)41:14<2411:SOANAT>2.0.ZU;2-T
Abstract
In order to develop an artificial photoresponsive siderophore by utilizing the photo-isomerization of an azobenzene group, a novel trihydroxamate side rophore based on an azobenzene skeleton was synthesized. The 1:1 and 2:2 st oichiometry of the ferric complex can be almost perfectly regulated reversi bly by irradiation with UV and visible light, respectively. (C) 2000 Elsevi er Science Ltd. All rights reserved.