Indium compound-catalyzed deoxygenative allylation of aromatic ketones by a hydrosilane-allylsilane system

Authors
Yasuda, M Onishi, Y Ito, T Baba, A
Citation
M. Yasuda et al., Indium compound-catalyzed deoxygenative allylation of aromatic ketones by a hydrosilane-allylsilane system, TETRAHEDR L, 41(14), 2000, pp. 2425-2428
Citations number
21
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
14
Year of publication
2000
Pages
2425 - 2428
Database
ISI
SICI code
0040-4039(20000401)41:14<2425:ICDAOA>2.0.ZU;2-#
Abstract
A combination of chlorodimethylsilane and allyltrimethylsilane effectively promoted the deoxygenative allylation of aromatic ketones in the presence o f a catalytic amount of an indium compound to give the terminal alkenes. In dium trihalide or metallic indium showed high catalytic activity. (C) 2000 Elsevier Science Ltd. All rights reserved.