The effect of an oxidative pretreatment on the anaerobic digestion of sewag
e sludge was investigated. Sewage sludge from a domestic wastewater treatme
nt plant was partially oxidized by ozone. The pretreatment could alter up t
o 67% of the organic matter: 29 +/- 3% was solubilized, 38 +/- 9% was remov
ed. Anaerobic degradability tests indicated that the pretreatment step enha
nced the subsequent anaerobic sludge digestion. The methane production was
increased by a factor of 1.8 after an ozone treatment at a dose of 0.1 g O-
3/g chemical oxygen demand (COD), while the methane production rate was 2.2
times higher compared to the untreated sludge. Higher ozone doses, althoug
h still positive, were found to have a less pronounced effect. Limited ozon
e treatment appears compatible with subsequent digestion of biosolids and e
conomically feasible. (C) 2000 Elsevier Science Ltd. All rights reserved.