Ternary halides of the type A(3)MX(6). IX crystal structures of Na3TiCl6 and K3TiCl6

Authors
Hinz, D Gloger, T Meyer, G
Citation
D. Hinz et al., Ternary halides of the type A(3)MX(6). IX crystal structures of Na3TiCl6 and K3TiCl6, Z ANORG A C, 626(4), 2000, pp. 822-824
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
626
Issue
4
Year of publication
2000
Pages
822 - 824
Database
ISI
SICI code
0044-2313(200004)626:4<822:THOTTA>2.0.ZU;2-S
Abstract
Light yellow single crystals of Na3TiCl6 and K3TiCl6 are obtained from the binary components, TiCl3 and NaCl and KCl, respectively, in 1:3 molar ratio s. Na3TiCl6 crystallizes with the cryolite type of structure (monoclinic, P 2(1)/n, Z = 2, a = 668,02(8), b = 709,13(6), c = 981,38(12) pm, beta = 90,3 1(2)degrees) while K3TiCl6 belongs to the K3MoCl6 type of structure (monocl inic, P2(1)/c, Z = 1, a = 1262,6(2), b = 751,36(8), c = 1210,7(2) pm, beta = 108,30(2)degrees).