Ba-2[Tl(OH)(6)]OH, the first hydroxothallate(III)

Authors
Hinz, D
Citation
D. Hinz, Ba-2[Tl(OH)(6)]OH, the first hydroxothallate(III), Z ANORG A C, 626(4), 2000, pp. 1012-1015
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
626
Issue
4
Year of publication
2000
Pages
1012 - 1015
Database
ISI
SICI code
0044-2313(200004)626:4<1012:BTFH>2.0.ZU;2-G
Abstract
Colourless, isometric crystals of Ba-2[Tl(OH)(6)]OH grew during several wee ks at room temperature through the reaction of Tl2O3 . xH(2)O in a concentr ated NaOH solution in the presence of barium hydroxide. Ba-2[Tl(OH)(6)]OH ( monoclinic. C2/c, a = 1186.3(2) pm, b = 646.01(8) pm, c = 1057.0(2) pm, bet a = 95.63(2)degrees) crystallizes in a distorted stuffed K2PtCl6 type of st ructure that is closely related to of M-2[Zn(OH)(6)], M = Sr, Ba, Ba-2[Mn(O H)(6)] Ba-2[Cu(OH)(6)], respectively.