Bis(4-hydroxybenzoato-O)(1,4,8,11-tetraazacyclotetradecane-kappa N-4)-nickel(II): a three-dimensional framework built from O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds

Authors
Glidewell, C Ferguson, G Gregson, RM Lough, AJ
Citation
C. Glidewell et al., Bis(4-hydroxybenzoato-O)(1,4,8,11-tetraazacyclotetradecane-kappa N-4)-nickel(II): a three-dimensional framework built from O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, ACT CRYST C, 56, 2000, pp. 174-176
Citations number
24
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
2
Pages
174 - 176
Database
ISI
SICI code
0108-2701(200002)56:<174:BN>2.0.ZU;2-4
Abstract
The title compound, [Ni(C7H5O3)(2)(C10H24N4)], contains octahedral Ni-II in a centrosymmetric trans configuration with Ni-N distances of 2.0637 (17) a nd 2.0699 (16) Angstrom and an Ni-O distance of 2.1100 (14) Angstrom. The m olecules are linked by a single type of O-H ... O hydrogen bond [O ... O 2. 618 (2) Angstrom and O-H ... O 161 degrees] into two-dimensional sheets; a single type of N-H ... O hydrogen bond [N ... O 2.991 (2) Angstrom and N-H ... O 139 degrees] links these sheets into a three-dimensional framework.