(Dicyclohexyldithiophosphinato-S,S ')-[2-(2-pyridyl-N)phenyl]mercury(II)

Citation
Js. Casas et al., (Dicyclohexyldithiophosphinato-S,S ')-[2-(2-pyridyl-N)phenyl]mercury(II), ACT CRYST C, 56, 2000, pp. 182-183
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
2
Pages
182 - 183
Database
ISI
SICI code
0108-2701(200002)56:<182:('>2.0.ZU;2-A
Abstract
The crystal structure of the title compound, [Hg(C11H8N)(C12H22PS2)], consi sts of molecules in which the HE atom is coordinated strongly to the C atom in position 2 of the phenyl group and to one of the dithiophosphinate S at oms, and at longer distances to the pyridine N atom and the other S atom. T he C-Hg-S fragment involving the S atom more strongly bound to Hg is almost linear [C-Hg-S = 178.9 (3)degrees].