An alkyl-palladium(II) complex with a bidentate phosphine ligand: [1,3-bis(diphenylphosphino)propane-P,P ']dimethylpalladium(II) toluene hemisolvate

Authors
Abu-Surrah, AS Debaerdemaeker, T Huhn, W Rieger, B Klinga, M Repo, T Leskela, M
Citation
As. Abu-surrah et al., An alkyl-palladium(II) complex with a bidentate phosphine ligand: [1,3-bis(diphenylphosphino)propane-P,P ']dimethylpalladium(II) toluene hemisolvate, ACT CRYST C, 56, 2000, pp. E42-E43
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
2
Pages
E42 - E43
Database
ISI
SICI code
0108-2701(200002)56:<E42:AACWAB>2.0.ZU;2-2
Abstract
In the title compound, [Pd(CH3)(2)(C27H26P2)]. 0.5C(7)H(8), the Pd atom is at the centre of an approximately square-planar arrangement of two P atoms and two methyl groups. The P-Pd-P angle [93.19 (3)degrees] is significantly larger than that in the corresponding dichloride complex [Pd(dppp)Cl-2]. T he toluene molecule is disordered across an inversion centre.