Inhibition of a palladium(II) catalyst upon formation of a di-mu-chloro complex: di-mu-chloro-bis[1,2-bis(diphenylphosphino)ethane-P,P ']-dipalladium(II) bis(tetrafluoroborate) bis(deuterochloroform) solvate

Authors
Abu-Surrah, AS Klinga, M Repo, T Leskela, M Debaerdemaeker, T Rieger, B
Citation
As. Abu-surrah et al., Inhibition of a palladium(II) catalyst upon formation of a di-mu-chloro complex: di-mu-chloro-bis[1,2-bis(diphenylphosphino)ethane-P,P ']-dipalladium(II) bis(tetrafluoroborate) bis(deuterochloroform) solvate, ACT CRYST C, 56, 2000, pp. E44-E45
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
2
Pages
E44 - E45
Database
ISI
SICI code
0108-2701(200002)56:<E44:IOAPCU>2.0.ZU;2-P
Abstract
The title compound was formed upon slow evaporation of a solution of the so lvated dicationic complex bis(acetonitrile)-bis[1,2-bis(diphenyl-phosphino) ethane]palladium(II) bis-(tetrafluoroborate) in deuterated chloroform. The dinucleur palladium complex forms triclinic crystals and there is an invers ion center between the Pd atoms. Compared to the corresponding monomeric co mpound, the Cl-Pd-Cl angles decrease upon briding from 94.19 (7) to 86.96 ( 4)degrees.