A pseudosymmetric triclinic modification of triphenyltin isopropylxanthate

Authors
Citation
Sw. Ng et Ad. Rae, A pseudosymmetric triclinic modification of triphenyltin isopropylxanthate, ACT CRYST C, 56, 2000, pp. E47-E48
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
2
Pages
E47 - E48
Database
ISI
SICI code
0108-2701(200002)56:<E47:APTMOT>2.0.ZU;2-8
Abstract
All three independent molecules in the triclinic modification of (O-isoprop yl dithiocarbonato-S)triphenyltin, [Sn(C6H5)(3)(C4H7OS2)], show tetrahedral coordination at their Sn atoms. Bond dimensions involving the Sn atoms are similar to those found in the monoclinic modification of the same compound . Two of the independent molecules are related by a pseudotranslation allow ing a stacking fault that reduces the intensities of h + k odd reflections.