Among the Nigerian cast copper-alloy artefacts, the chronology of the Benin
memorial heads has been the most fully worked out. Therefore, a study focu
sed upon their elemental compositions is particularly likely to be interpre
table in terms of development of the alloys used in their making. The eleme
ntal analyses, both published and unpublished, of 66 Benin heads, supplemen
ted with seven analyses of some artefacts excavated from a well-dated, very
early Benin site, have been collected, analysed statistically and compared
to the elemental analyses of 11 heads and figures from Udo. All but a very
few of the Benin heads and artefacts separate into five compositional grou
ps, indicating a chronological sequence of different alloying traditions. A
ll but one of the Udo objects fall into a distinctly separate compositional
group, together with two Medicine heads. The compositional groups correlat
ed remarkably well with the stylistic types proposed by Dark.