We present high-resolution spectroscopy and images of a photodissociation r
egion (PDR) in M16 obtained during commissioning of the near-infrared spect
rometer (NIRSPEC) on the Keck IT telescope. PDRs play a significant role in
regulating star formation, and M16 offers the opportunity to examine the p
hysical processes of a PDR in detail. We simultaneously observe both the mo
lecular and ionized phases of the PDR and resolve the spatial and kinematic
differences between them. The most prominent regions of the PDR are viewed
edge-on. Fluorescent emission from nearby stars is the primary excitation
source, although collisions also preferentially populate the lowest vibrati
onal levels of H-2. Variations in density-sensitive emission-line ratios de
monstrate that the molecular cloud is clumpy, with an average density n = 3
x 10(5) cm(-3). We measure the kinetic temperature of the molecular region
directly and find that T-H2 = 930 K. The observed density, temperature, an
d UV flux imply a photoelectric heating efficiency of 4%. In the ionized re
gion, n(i) = 5 x 10(3) cm(-3) and T-H II = 9500 K. In the brightest regions
of the PDR, the recombination line widths include a nonthermal component,
which we attribute to viewing geometry.