New structurally rigid palladium catalysts for the alternating copolymerization of carbon monoxide and ethene

Authors
Bianchini, C Lee, HM Meli, A Oberhauser, W Vizza, F Bruggeller, P Rainer, HB Langes, C
Citation
C. Bianchini et al., New structurally rigid palladium catalysts for the alternating copolymerization of carbon monoxide and ethene, CHEM COMMUN, (9), 2000, pp. 777-778
Citations number
20
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
9
Year of publication
2000
Pages
777 - 778
Database
ISI
SICI code
1359-7345(2000):9<777:NSRPCF>2.0.ZU;2-3
Abstract
Decreasing the flexibility of the Ph2PCH2CH2PPh2 (dppe) backbone by making the central carbon atoms part of a cyclobutane ring leads to the formation of Pd( II) catalysts for CO/ethene copolymerization that are more efficient than those of dppe by a factor of ten.