We propose that the hemispheric asymmetry (Fig. 1) of mare basalts may be e
xplained as a result of hydrodynamic instabilities associated with a layer
of mixed ilmenite-rich cumulates (IC) and olivine-orthopyroxene (OPx) overl
ying a metallic core. This mixed layer (MIC) should form shortly after the
solidification of the magma ocean (P.C. Hess and E.M. Parmentier, Earth Pla
net. Sci. Lett. 134 (1995) 501-514) because of gravitational differentiatio
n of chemically dense IC material that is expected to form below the anorth
ositic crust in the final stages of magma ocean crystallization (A.E. Ringw
ood and S.E. Kesson, Proc. Lunar Planet. Sci. Conf. 7 (1976) 1697-1722). IC
material is rich in heat producing elements, and thermal expansion due to
radiogenic heating causes the MIC layer to become less dense than overlying
mantle. The time required for the MIC layer to become thermally buoyant ma
y explain a delay of mare volcanism until about 500 Ma after solidification
of the magma ocean. Our analyses of the resulting Rayleigh-Taylor instabil
ity and numerical modeling of thermo-chemical convection show that the inst
abilities produce spherical harmonic degree I thermal and compositional str
ucture if a lunar metallic core is sufficiently small, less than 250 km in
radius. (C) 2000 Elsevier Science B.V. All rights reserved.