An unexpected reaction of 3-phenyl-3-chloro-2-oxopropanoic acid derivatives with sodium azide. A novel synthesis of highly functionalized oxazolines

Citation
Va. Mamedov et al., An unexpected reaction of 3-phenyl-3-chloro-2-oxopropanoic acid derivatives with sodium azide. A novel synthesis of highly functionalized oxazolines, HETEROCYCLE, 52(3), 2000, pp. 1385
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLES
ISSN journal
03855414 → ACNP
Volume
52
Issue
3
Year of publication
2000
Database
ISI
SICI code
0385-5414(20000301)52:3<1385:AURO3A>2.0.ZU;2-0
Abstract
The reaction of 3-phenyl-3-chloro-2-oxopropanoic acid derivatives with sodi um azide proceeded unexpectedly with the formation of oxazolines via interm ediately forming alpha-azido- and/or alpha-imino ketones.