H. Uchiyama et al., X-ray photoemission spectroscopy study for the flat YBa2Cu3Oy single-crystal surface prepared by chemical etching and O-2 annealing, JPN J A P 1, 39(3A), 2000, pp. 1320-1322
The effect of chemical etching with a HCl/methanol solution on a polished s
ample of single-crystal YBa2Cu3Oy (001) was investigated by emission-angle-
dependent X-ray photoemission spectroscopy (XPS). By chemical etching, the
extrinsic Ba state in the surface region was removed without the effect of
halogen. The bulk state of Y was also restored in the surface by subsequent
annealing in an oxygen atmosphere at 400 degrees C.