When plasma immersion ion implantation is performed in the condensable plas
ma stream produced by a cathodic vacuum arc, deposition as well as implanta
tion usually occurs. In this article we describe a method of achieving pure
implantation by orienting the substrate so that it is shadowed from the pl
asma beam. Implantation depth profiles measured in glassy carbon and CR39 p
olymer using Rutherford backscattering are compared to illustrate the effec
tiveness of the technique for conducting and insulating substrates. Chargin
g of the insulating substrate was found to cause a reduction in implantatio
n depth compared to a conducting substrate. The depth profiles in glassy ca
rbon were comparable to those achieved by conventional extracted ion beam i
mplantation. Implantation of magnesium into hydroxyapatite and alumina was
carried out to improve the bone cell adhesion onto these materials for pros
thetic applications. (C) 2000 American Institute of Physics. [S0021-8979(00
)05004-0].