Electrical double-layer structure at the rutile-water interface as observed in situ with small-period X-ray standing waves

X-Ray standing wave (XSW) measurements were made of Rb and Sr adsorbed from aqueous solutions at the rutile (110)-water interface. These experiments w ere performed to address the extent to which direct measurements of electri cal double-layer structure are possible. The experimental results show that the Bragg XSW technique, using small-period standing waves generated by Br agg diffraction from the substrate, can precisely measure ion locations wit hin the condensed layer and the in situ partitioning of ions between the co ndensed and diffuse layers. Differences in condensed layer ion positions we re observed for Sr ions (measured in situ) as compared with Rb ions (in sit u) and also for Sr ions (ex situ). An additional constraint on the ex situ Sr site geometry was provided by polarization-dependent surface EXAFS measu rements. Such measurements can provide important constraints for the develo pment and verification of electrical double-layer theory especially as appl ied to ion adsorption at the solid-water interface. (C) 2000 Academic Press .