Non-equilibrium interface of a two-dimensional low-temperature crystal

Citation
Va. Shneidman et al., Non-equilibrium interface of a two-dimensional low-temperature crystal, J CRYST GR, 212(3-4), 2000, pp. 564-573
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CRYSTAL GROWTH
ISSN journal
00220248 → ACNP
Volume
212
Issue
3-4
Year of publication
2000
Pages
564 - 573
Database
ISI
SICI code
0022-0248(200005)212:3-4<564:NIOATL>2.0.ZU;2-C
Abstract
We study the interface in an Ising system with nearest-neighbor interaction on a square lattice at very low temperatures, when the Wulff shape of a nu cleus is almost a perfect square. Spins are randomly flipped via Metropolis -type dynamics. At moderately strong undercoolings, the step nucleation rat es can be evaluated from the first principles. This permits the description of the growth of an infinite interface using a step-on-step nucleation pic ture. The averaged shape of the interface is universal (i.e., it does not d epend on any parameters as long as the interface remains stable), and its g rowth rate, in appropriate variables, also has no free parameters. For fini te sizes of two-dimensional crystals their growth can be dominated by nucle ation of single steps. and becomes size-dependent. For both infinite- and f inite-size interfaces growth rates are in good agreement with large-scale M onte Carlo simulations. At high undercoolings the interface becomes very ro ugh, in which case the crystals switch to circular shapes, in contrast to t he equilibrium Wulff expectation. (C) 2000 Elsevier Science B.V. All rights reserved.