C. Hartmann et al., ROBUST ORTHOGONAL REGRESSION FOR THE OUTLIER DETECTION WHEN COMPARING2 SERIES OF MEASUREMENT RESULTS, Analytica chimica acta, 344(1-2), 1997, pp. 17-28
The application of a robust orthogonal regression procedure is describ
ed for the outlier detection during the evaluation of a method compari
son study and, in general, when comparing two series of measurement re
sults. The procedure is based on the least median of the squared ortho
gonal residuals (orthogonal LMS). It is concluded that the orthogonal
LMS procedure is a useful screening tool to detect outlying values in
a data set. Especially for data sets with extreme Values it is recomme
nded to combine the robust data evaluation with a visual display. For
the comparison of heteroscedastic methods, the program can easily be a
dapted to a weighted orthogonal LMS variant.