PrCo2Si2 has a collinear antiferromagnetic structure with a wave vector Q(1
) = (0, 0, 1) for T < T-1 = 9 K, a high-order commensurate one with Q(2) =
(0,0, 25/27) for T-1 less than or equal to T less than or equal to T-2 = 17
K and with Q(3) = (0, 0, 7/9) for T-2 less than or equal to T < T-N = 30 K
. Molecular field calculations of the moment arrangements and magnetization
processes of the compound were made with a molecular held model and the he
ld-temperature magnetic phase diagram was reproduced. The magnetic transiti
ons are discussed in connection with the wave-dependent molecular field coe
fficients of the compound. (C) 2000 Elsevier Science B.V. All rights reserv
ed.