Ni-W alloys and their composite deposits are electroplated on the metals wh
en an appropriate complex agent is selected on the base of the theories of
electrochemistry and complex chemistry, and the principle of induced codepo
sition. Effects of the bath composition, pH value, temperature and current
density on the electrode position of Ni-W alloys and their composite deposi
ts have been investigated, and the effect of heat treatment temperature on
the hardness, structure and cohesive force of the amorphous Ni-W alloys and
their composite deposits are also discussed. Results showed that the alloy
s containing more than 44 wt pet W content and the composite deposits conta
ining 7.8 wt pet SiC content could be obtained by making use of the appropr
iate bath composition and plating conditions. Alloys and their composite de
posits with over 44 wt pet W content show amorphous structure. The hardness
of amorphous Ni-W alloys and their composite deposits increases obviously
when heated, and can reach to 1350 HV and 1520 HV respectively for 46 wt pe
t W content. The cohesion on Cu, carbon steel and stainless steel is very g
ood.