Intramolecular Friedel-Crafts acylation of acyclic (eta(4)-diene)Fe(CO)(3)complexes

Authors
Yeh, MCP Chang, SC Chang, CJ
Citation
Mcp. Yeh et al., Intramolecular Friedel-Crafts acylation of acyclic (eta(4)-diene)Fe(CO)(3)complexes, J ORGMET CH, 599(2), 2000, pp. 128-134
Citations number
29
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
599
Issue
2
Year of publication
2000
Pages
128 - 134
Database
ISI
SICI code
0022-328X(20000415)599:2<128:IFAOA(>2.0.ZU;2-B
Abstract
Intramolecular cyclization of (eta(4)-diene)Fe(CO)(3) complexes bearing a c arboxylic acid chloride functionality at the terminal side chain of the die ne ligand produces (sigma, eta(3)-allyl)Fe(CO)(3) complexes, whereas treatm ent of the acid chloride complexes with Et3N and AlCl3 provides (eta(4)-die ne)Fe(CO)(3) complexes containing a cyclopentanone moiety. (C) 2000 Elsevie r Science S.A. All rights reserved.