Multiwall carbon nanotubes (MWCNTs) were fabricated by a new cathodic vacuu
m are method, in which the anode itself was the vacuum chamber and was iner
t. The cathodic vacuum are discharge was performed at 0.5 Pa of He and H-2
gas atmospheres using a de are current of 100 A. The cathode materials were
pure graphite and various metal-containing graphite electrodes. Microscopi
c observation revealed that MWCNTs were produced at the cathode crater gene
rated by the cathode spot and on the surface of macrodroplets emitted from
the cathode spot. A diamond-like carbon film that embedded the macrodroplet
s with MWCNTs was also deposited.