We describe polarizing films formed from the lyotropic liquid crystalline p
hases of dyes dissolved in water. The dye polarizers possess a high dichroi
c ratio close to that of conventional polarizers. Tn addition, the dried dy
e films provide a uniform homogeneous orientation for thermotropic nematic
materials. Therefore, thin dye films can simultaneously serve as internal p
olarizers and as alignment agents. These properties make them especially su
itable for twisted nematic devices based on low cost birefringent plastic s
ubstrates.