M. Veber et G. Berruyer, Ionic liquid crystals: synthesis and mesomorphic properties of dimeric 2,4,6-triarylpyrylium tetrafluoroborates, LIQ CRYST, 27(5), 2000, pp. 671-676
The synthesis of some dimeric pyrylium salts is described. The link between
the two cationic parts of the molecule can be flexible or rigid. Surprisin
gly, the starting dimeric chalcones with a rigid link exhibit monotropic co
lumnar hexagonal phases. Results concerning the spectroscopic and mesomorph
ic properties of the pyrylium salts and the chalcones are given.