In this work a novel method to characterize quantum well (QW) structures an
d devices is presented. The method is based on the well-known surface photo
voltage spectroscopy (SPS) and on numerical simulations. It is shown that t
he surface photovoltage is sensitive to the electron hole energy transition
levels in the well layer as well as to features of other regions of the st
ructure. The photovoltaic response as function of well width is numerically
studied and is found to increase with decreasing well width. As a result o
f the spectra analysis growth parameters such as quantum well width and ter
nary layer composition (both of quantum well and cladding layers) are accur
ately determined. In addition, structure properties such as electric fields
and effective carriers lifetime at the well are estimated. Finally it is s
hown that operating device parameters such the lasing wavelength may also b
e obtained. The results demonstrate the power of SPS as a characterization
method for QW structures and devices in a contactless and non-destructive m
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