Results from measurements and calculations of relative L- and M-shell ioniz
ation cross sections by electron impact are presented. Measurements were pe
rformed fur elements Te, Au and Bi on an electron microprobe with specimens
consisting of extremely thin films of the studied element deposited on thi
n, self-supporting, carbon layers. The relative variation of the ionization
cross section was obtained by counting the number of characteristic X-rays
from the considered element and shell, for varying incident electron energ
ies, from the ionization energy up to 40 keV. Measured data were corrected
to account for the energy-dependent spread of the electron beam within the
active film and for the ionization due to the electrons backscattered from
the carbon layer, using Monte Carlo simulation. Cross sections were evaluat
ed in the Born approximation using an optical-data model with numerically e
valuated dipole photoelectric cross sections. Calculated ionization cross s
ection were converted to vacancy production cross sections, which can be di
rectly compared with our experimental data.