Gd substitution effect on the formation of Bi-based superconducting glass ceramics

Citation
M. Pop et al., Gd substitution effect on the formation of Bi-based superconducting glass ceramics, MOD PHY L B, 14(2), 2000, pp. 59-63
Citations number
10
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
MODERN PHYSICS LETTERS B
ISSN journal
02179849 → ACNP
Volume
14
Issue
2
Year of publication
2000
Pages
59 - 63
Database
ISI
SICI code
0217-9849(20000120)14:2<59:GSEOTF>2.0.ZU;2-4
Abstract
The effect of calcium substitution by gadolinium on the superconducting pha ses formation in BSCCO-type compounds is studied by X-ray diffraction and a c susceptibility measurements on the undoped and Gd-doped Bi1.8Pb0.2Sr2CaCu 2Oz and Bi1.8Pb0.2Sr2Ca2Cu3Oz systems. The addition of gadolinium to the sa mples favors the 2212 phase formation in both 2212 and 2223 starting compos itions. It is suggested that a correlation exists between the stabilization effect of gadolinium on the 2212 phase formation and the Gd3+ coordination in oxide compounds.