Silylcupration of allenes and subsequent electrophilic trapping by allylicphosphates. A novel approach to silylated 1,4-diene systems

Authors
Liepins, V Karlstrom, ASE Backvall, JE
Citation
V. Liepins et al., Silylcupration of allenes and subsequent electrophilic trapping by allylicphosphates. A novel approach to silylated 1,4-diene systems, ORG LETT, 2(9), 2000, pp. 1237-1239
Citations number
30
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
9
Year of publication
2000
Pages
1237 - 1239
Database
ISI
SICI code
1523-7060(20000504)2:9<1237:SOAASE>2.0.ZU;2-Z
Abstract
Silylcupration of allenes with a lower order silylcuprate reagent followed by an electrophilic trapping reaction with allylic diphenyl phosphates has been studied. This reaction provides a new route to 1,4-diene systems havin g an allylsilane moiety.