Temporary in situ aluminum and zinc tethering in Diels-Alder reactions

Authors
Bertozzi, F Olsson, R Frejd, T
Citation
F. Bertozzi et al., Temporary in situ aluminum and zinc tethering in Diels-Alder reactions, ORG LETT, 2(9), 2000, pp. 1283-1286
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
9
Year of publication
2000
Pages
1283 - 1286
Database
ISI
SICI code
1523-7060(20000504)2:9<1283:TISAAZ>2.0.ZU;2-F
Abstract
Temporary tethering using aluminum or zinc in Diels-Alder reactions made po ssible the use of otherwise "noncompatible" combinations of dienes and dien ophiles, resulting in the one-step formation of substituted cyclohexene 1,2 -bis-methanols. Excellent regioselectivity and also significant stereoselec tivity were obtained.